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The kinetics of thermal degradation of ascorbic acid was studied in a Maltodextrin matrix at different temperatures between 75 and 140 °C. Isothermal experiments were performed with samples earlier equilibrated in environments of known aw at 4 °C, enclosed in hermetically sealed vials, with water contents (w) between 0.17 and 1.68 g water/g solids. Sampling times were selected according to an optimal experimental design in terms of minimum confidence regions of the parameters estimated, using the Bigelow model and estimates from preliminary experiments. The results showed a quadratic dependence of the reference D-value and linear dependence of the z-value with moisture content: Dr(140 °C) = 150.07 − 290.73w + 269w2 (min); z = 12.14 + 22.99w (°C) and showed the applicability of D-optimal designs for determining kinetic parameters in complex situations, with limited experimental requirements. The dependence of the rate constants with water content could not be described by the WLF model in qualitative terms, although in absolute values this model could be used with constants similar to those expected from glass transition theory. The thermodynamic analysis of the results showed a good application of the compensation theory in the whole range of water contents.
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The author emphasizes the crucial relevance of religious liberty and freedom of expression for a harmonious and peaceful development of modern societies. He follows the prophetic Declaration of Religious Freedom of Second Vatican Council (1965) with its constitutional limitation of governmental powers in matters of religion. The high value of religious freedom is judged as bulwark of all human rights and true capstone of sound human and societal developments, which have to be guarded against any form of infringements. In this regard, a reasonable education in religious freedom and liberty is indispensable for young people of the twenty-first century. Education in religious freedom in the context of moral and religious formation is based on the dignity of every human person and promotes a deeper mutual and cultural understanding by respecting the conscience of every human person. It thus carries the potential to diminish conflicts and clashes in a sustainable way. Educational reforms in countries have to include the high value of religious liberty and freedom as a main element and condition for human dignity and a peaceful global development.
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A growing focus on God’s mercy and forgiveness emerged in the wake of the recent Pontificates of John Paul II, Benedict XVI, and Francis. Our time with its multiple crises cries for healing, forgiveness, and the experience of God’s mercy. In social, political, and global terms, humanity craves for “lasting peace, born of the marriage of justice and mercy” (John Paul II, 2001, no. 15). The experience of God’s forgiveness, merciful healing and new life has been expressed many times in the Bible. But, theologically, it has never been formulated as directly as in Hosea 11:8, when God’s own heart becomes “turned over”, “converted” following the blaze of his own overwhelming compassion, paving the way for a fundamental spiritual transformation, rooted in forgiveness and mercy, that opens wellsprings of dignity, healing, and new life for all.
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For sustainability researchers and global policy makers it is lucid clear that a radical turnaround of modern societies is needed to approach sustainable development paths. Pope Francis takes his stand on a basic paradigm shift in his Encyclical Letter Laudato Si’: Care for our Common Home (2015). He calls for a radical shift of mindsets and ecological and cultural conversion which are needed for sustainability and a life in dignity for all. The author compares aspects from sustainability research and Laudato Si’ and shows how science and Francis spiritual-theological take converge. Both call for the need of new mindsets and spiritual resources to nourish just life-styles and sustainable societies.
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The article sets off from a speech given by Benedict XVI in the German Bundestag in 2011, where he requested an ecological learning process to aim at sustainable human development. Appreciating the Ecological Movement, he asked to learn to listen to Nature’s language and act accordingly, which he applies analogically to “human ecology”. The article bridges elements of “Listening to Nature” and the Natural Moral Law Tradition in Benedict’s speech and in Francis’ Encyclical Letter Laudatu Si’ inview of serving human flourishing in an ecological civilization. Keywords: Natural Moral Law; Nature, Laudatu Si’, Benedict XVI, Francis; Ecological Civilization/生態文明, Sustainable Development, Ecology of Man.
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